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Corrosion of low carbon steel sheet takes many forms. It can be
uniform, spreading over the entire exposed surface of a metal sheet; or it can
be localized, occurring where special conditions create a corrosive environment.
It can occur microscopically small, or, as is more often the case for low carbon
steel sheet, it occurs in a form that is macroscopic or clearly visible.
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Crevice Corrosion
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Poultice
Corrosion
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Erosive Corrosion
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Fretting
Corrosion
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Uniform corrosion of steel sheet is usually readily visible, and as the name
implies, the corrosion occurs on the entire surface. In addition to uniform
corrosion, there are several other types of corrosion that are clearly visible.
Examples include crevice corrosion that occurs within fissures and
narrow openings where water may be trapped in such locations at gaskets, lap joints, bolts,
rivets, weldments or scratches. Poultice corrosion is
common on vehicles, occurring when dirt and other debris accumulate inside
wheelwells and other under-vehicle parts. The accumulation of debris
retains road salt and water and acts to keep the metal surface damp, promoting
corrosive chemical action. Erosive corrosion occurs when an
abrasive stream of water strikes a metallic surface. Still another form of
corrosion, known as fretting, occurs when mating surfaces are subjected
to an electrolytic solution (often a thin film of moisture) in combination with
vibration.
Typically, for items
manufactured using steel sheet, the causes of corrosion are clearly understood.
For instance, the bottom skirts and panels of clothes washers may be splashed
with water containing detergents and bleaches. The presence of detergents and
bleaches in the water may accelerate the corrosion reaction substantially. Metal
building roofing may be subjected to acid rain which contains sulfurous
compounds that accelerate corrosion. Of course, the very familiar
corrosive reaction on vehicles in the presence of salt-containing road splash is
well documented.
It
is these types of environments that have led to the common use of coated steel
sheet products. The understanding of corrosion and the documented benefits
associated with the use of metallic coatings on steel have led us to where we
are today. That is, the market demand for metallic-coated steel sheet products
is increasing dramatically as the value of using coated steel sheet becomes more
and more apparent.
Technology has advanced sufficiently today so that the influence of various
contaminants in the atmosphere can be predicted. For instance, the
corrosion-producing effects of the atmosphere vary from locality to locality
according
to climatic conditions of temperature, humidity, amount of rainfall and the
degree and nature of air pollution present. Corrosion is
severe-to-moderate along the coasts due to seawater spray carried inland by
winds and storms. The application of a coated steel sheet product in any of
these types of environments can thus be engineered to provide the best
combination of coating type, coating thickness, etc. to achieve the
desired life of the product.
U. S. Steel's Coated Steel Sheet, when properly selected and applied, can
combat corrosion successfully in many applications.
Coatings protect steel sheet from corrosive attack by acting as a barrier to
exclude air, water and other corrosion promoters from contact with the steel
substrate.
All the metallic coatings on U. S. Steel Coated
Steel Sheet products, zinc (galvanized), galvannealed (zinc-iron alloy), zinc-aluminum (GALVALUME®),
terne (lead-tin alloy coating) and paints provide excellent barrier
protection.
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In addition to barrier protection, zinc and zinc alloys have the ability to
react at scratches and other damage through an electrochemical (galvanic) action
between steel and zinc. This galvanic action makes it possible for the
zinc to protect breaks in the coating and prevent further damage. |
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In this galvanic process, zinc actually sacrifices itself to protect
and maintain the structural integrity of the steel. This well-established
behavior of a zinc coating on steel is known as sacrificial protection.
This sacrificial or galvanic protection is provided by zinc, zinc-iron and
zinc-aluminum coatings.
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