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| Properties of the Base Steel |
| U. S. Steel Galvanized Sheet is available in six
metallurgical designations, providing different degrees of
formability and strength to the base sheet. |

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Commercial Steel (CS)
This
designation is for the basic product, useful for many applications
requiring the strength of steel combined with the workability
needed for bending and moderate forming. It provides the strength
and formability levels that most users need for general purpose
applications.
CS sheet is subject to a phenomenon called aging; therefore, if
the sheet must be free from strain lines (stretcher strains,
flutes, etc.) after fabrication, it should be roller leveled just
before the forming operation.
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Forming Steel (FS)
The primary difference between FS and CS sheet is that
FS sheet is processed to be more formable, i.e., easier to bend,
etc. FS sheet is slightly more formable than CS and is typically
used for applications where breakage (splitting) might be
encountered when CS sheet is not quite formable enough to make a
part. Often, FS is selected to allow easier bending with less
springback. FS sheet is produced from specially selected steels,
processed for improved and more uniform formability properties.
FS sheet is subject to the same aging phenomenon as CS sheet;
therefore, to avoid strain lines, FS sheet should be roller leveled
just before the forming operation.
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Deep
Drawing Steel (DDS)
DDS
sheet is produced from aluminum-killed steel employing special
steelmaking practices. It can be produced using restricted
low-carbon steels or interstitial-free steels depending on the
application requirement and the producing facility. It has forming
characteristics superior to CS and FS sheet. These characteristics
make it excellent for applications involving deep drawing or
combinations of drawing and stretching.
DDS sheet is non-aging. DDS sheet is recommended for use when
improved drawability is required and the effects of aging (slight
hardening, loss of ductility, and strain lines) are undesirable or
roller-leveling equipment is not available.
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Extra Deep Drawing Steel (EDDS)
Coated
sheet of this quality is characterized by excellent uniformity and
exceptional formability. EDDS Sheet is produced from vacuum
degassed steel to achieve a very low carbon content. Also,
stabilizing elements such as titanium and niobium (columbium) are
added during steel production to combine with the residual
amounts of carbon and nitrogen remaining in the degassed steel to
make it "interstitial-free". The final product is excellent for
deep drawn parts in that the sheet exhibits a high resistance to
thinning during drawing.
EDDS Sheet is non-aging. Thus, coil breaks, strain lines and
fluting during fabrication are not encountered.
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Structural Steel (SS)
SS
sheet is recommended for applications in which specific mechanical
properties are required for strength in a finished part, usually in
load-bearing structures. Orders for SS usually require that minimum
yield and tensile strengths be met by the steel producer. The
required strength level is achieved through the use of carbon,
manganese, phosphorus, and/or nitrogen additions during
steelmaking. When specifying a SS grade, the user should carefully
consider the compatibility of the specified properties with forming
requirements. In general, steels produced to meet
increasing yield strength levels have a corresponding decrease in
ductility or formability.
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High
Strength Low Alloy (HSLA) Steel
HSLA steel sheet is defined as having a specified
minimum yield strengths of 35 ksi or higher. HSLA steels are
produced to meet minimum yield and/or tensile strength levels.
Often, these steels are intended for applications that require more
ductility (% elongation) and/or weldability than Structural Steels. For this reason,
they are generally produced using micro-alloying technology wherein
additions of elements such as titanium, niobium (columbium) and vanadium are
added during steelmaking. The most common types of HSLA steel sheets
exhibit yield strengths in the range of 35 to 70 ksi. Typically,
the tensile strength is 10 to 15 ksi higher than the yield
strength. Higher strength steels are available, but they often
exhibit relatively low formability.
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ASTM References for Hot-Dip Galvanized Sheet
The general requirements, including tolerances for thickness,
width, camber, shape, etc., for hot-dip galvanized sheet are
presented in ASTM Specification A924. Specific product designations
for hot-dip coated galvanized sheet are listed in ASTM
Specification A653. Included in this specification are steel
chemistry requirements, typical mechanical properties for the
general grades CS, FS, DDS, and EDDS designations, strength and
formability requirements for SS and HSLAS steels, and coating
weight requirements for the different coating designations.
The following table contains typical values for U. S.
Steel product when purchased to the above-listed designators. These
numbers represent typical data. A broad range can be expected
because the final sheet thickness has a significant influence on
the mechanical properties and formability. Normally, the yield
strength value tends to increase and the formability values tend to
decrease as the steel sheet thickness decreases.
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Typical Mechanical
Properties* for
U. S. Steel Hot-Dip Galvanized Sheet
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Steel
Designation
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Yield
Strength
(ksi)
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Tensile
Strength
(ksi)
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Elongation
(%)
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Hardness
RB
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Plastic
Strain
Ratio rm
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CS
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48
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59
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28
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62
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1.0
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FS
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40
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53
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31
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55
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1.0
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DDS
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26
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48
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38
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46
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1.6
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EDDS
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22
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44
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42
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41
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1.7
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*The typical mechanical
property values presented in this table are nonmandatory. They are
intended solely to provide the purchaser with as much information
as possible to make an informed decision on the steel to be
specified. Since the mechanical properties often vary as a function
of steel thickness, the yield strength for thicker steels may be
lower than the number listed; similarly, the yield strength for
thinner sheets may be higher than this number.
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Mechanical Property
Requirements for ASTM A653
Structural Steel Grades
(Minimum Values)
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Grade
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Yield
Strength
(ksi)
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Tensile
Strength
(ksi)
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Elongation
(%)
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33
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33
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45
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20
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37
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37
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52
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18
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40
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40
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55
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16
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50 A Class 1
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50
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65
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12
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50 B Class 2
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50
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···
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12
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| 50 Class 3 |
50 |
70 (B) |
12 |
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80
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80
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82 (A)
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···
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Where an ellipsis
(···) appears in the table, there is no requirement.
A - For sheet thicknesses of 0.028 and thinner,
no tension test is required if the hardness result is Rockwell B 85
or greater.
B - As there is no discontinuous yield curve, the yield strength
should be taken as the stress at 0.5% elongation under load or 0.2%
offset.
Coating Thickness
Coating thickness (measured as coating weight in ounces
per square foot or grams per square meter) is an important factor
in the effective application of galvanized sheet. The coating
weight should be chosen carefully, with full attention to the fabrication method and
type of environment in which the sheet will be expected to
serve. In general, the effectiveness of the zinc coating to
protect the steel substrate from corrosion in any given environment
is directly proportional to the coating thickness. For
example, for any specific set of environmental conditions, a G90
coating will last about 50 percent longer than a G60 coating, maintenance, painting and all other factors being equal.
Factors in addition to corrosion resistance must be considered
when selecting coating thickness. For example, the adherence
of the coating generally is inversely proportional to the
thickness; therefore, a thin coating is more desirable for
applications involving high amounts of forming. Also, spot
welding becomes more difficult as the coating thickness
increases.
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Coating Thickness -
English Units
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ASTM A653
Coating Designation1)
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Minimum
Coating Weight
oz/sq ft
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Triple Spot Average
Total Both Sides (2)
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Single Spot
Test
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One Side
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Total
Both Sides |
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G210
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2.10
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0.72
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1.80 |
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G185
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1.85
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0.64
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1.60 |
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G165
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1.65
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0.56
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1.40 |
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G140
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1.40
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0.48
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1.20 |
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G115
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1.15
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0.40
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1.00 |
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G90
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0.90
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0.32
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0.80 |
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G60
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0.60
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0.20
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0.50 |
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G40
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0.40
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0.12
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0.30 |
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G30
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0.30
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0.10
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0.25 |
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Coating Thickness -
English Units
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Coating
Designation
(1,3)
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Minimum
Coating Weight
g/sq m (4)
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G20/20
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20
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G40/40
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40
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G50/50
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50
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G60/60
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60
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G70/70
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70
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G90/90
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90
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G98/98
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98
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1. The coating designation number
is the term by which this product is ordered.
2. The weight of coating in oz. per sq. ft.
refers to the total coating on both surfaces. The triple spot
average encompasses an edge-center-edge sampling to determine
adequate coverage across the sheet width. Typically, about half
this coating is on each side.
3. Ordered coating weight is specified on a
per-side basis, e.g., 50/50 requires each surface to have a minimum
coating weight of 50 g/m2.
4. To convert coating weight from oz/sq ft to
g/sq m the following factor can be used: g/sq m = oz/sq ft x
305.15.
Note that, although a precise conversion
between ASTM A653 "G" categories (G30, G60, etc.) and the metric
categories (20/20, 40/40, etc.) cannot be made, a G60 coating
category (ASTM A653) is approximately equal to a 90/90 coating
category (metric).
Surface Finish
The hot dip galvanizing process results in a zinc
coating with a crystalline structure that is clearly visible on the
surface after coating. When the as-coated surface consists of
large, multi-faceted grains, the finish is termed "spangled". In
today's market, this large spangled appearance is called "Regular
Spangle". Typically, the spangled finish has some amount of surface
relief caused by the normal behavior of most metals, they shrink
when they solidify.
For some applications, especially when the
sheet will be painted, the spangled pattern may be undesirable for
reasons of appearance or incomplete paint coverage at the spangle
boundaries. If so, the size of the spangles can be
controlled.
U.S. Steel supplies galvanized sheet with
several different degrees of spangle appearance.
Regular Spangle
Sheet
Regular Spangle Sheet has a pattern that occurs from the normal solidification step
during the hot-dip process. The coating bath of molten zinc
contains small amounts of chemical elements that induce the
formation of the spangled finish as the coating freezes in the
cooling tower above the coating bath. These large, bright spangles
are clearly visible. They provide the readily-recognized,
faceted, metallic surface finish of galvanized sheet. Regular
Spangle finish has a discernible amount of surface
relief.
The spangle size is typically not a
function of the coating thickness. Large spangles can form on both
light and heavy coating-weight product. In general, however,
heavier coating weights result in more surface relief at the
spangle boundaries although the spangle size also affects the
amount of surface relief.
Minimum Spangle Galvanized Sheet
Minimum Spangle Galvanized Sheet has a finish in which the
individual spangles are very small, often barely visible. The small
spangles have much less surface relief than Regular Spangle
product. Typically, this finish provides a good surface for
application of paint when minimal spangle show-through is
desired. In addition, the reduced amount of surface relief
associated with Minimum Spangle vs. Regular Spangle allows more
complete paint coverage (less tendency for small paint skips) when
painting is done on a coil-paint line.
The Minimum Spangle finish can be produced
by several methods. One involves blowing either a water/air or
steam/air mixture against the molten zinc surface just ahead of the
time that the coating solidifies. Another common method of
production involves blowing zinc dust against the molten zinc just
ahead of the point where solidification begins. In both methods,
the spangle size is reduced by increasing the rate of nucleation as
the zinc solidifies.
During the past 10 years, there has been
an increasing need for minimum- to non-spangled galvanized sheet.
This need combined with new technology in the production of zinc
metal used for galvanizing has led to a new method of
maintaining a small to nonspangled finish. This method involves
the use of zinc coating baths that contain low amounts of
impurities that contribute to the spangle pattern during
solidification.
Historically, the most common impurity in
zinc metal was lead, at concentrations of about 0.10%, or less,
down to 0.03%. The presence of lead in zinc ores was the reason
that lead was commonly present in galvanizing baths. As the zinc
industry has moved to improved methods of zinc production, lead is
no longer a common impurity. As a result, small to non-spangled
finishes can be achieved without the need for artificial methods of
nucleating grains (water/air spray and /or zinc dust). This method
of making a small to non-spangled finish is called the "no-lead"
process. When produced by this method, the coating exhibits a
bright, reflective appearance.
Because elements such as lead impact the
fluidity of the coating bath, another important aspect of the
molten coating bath metal, many producers today use a bath
composition that has only a very small amount of lead, less than
0.02%, often lower. This small amount of lead enhances the fluidity
of the metal to achieve good "air knife wiping action".
U. S. Steel does not add lead to the
coating bath. Instead, small amounts of antimony are used to
achieve "good wiping action" or to make a spangled finish when
needed. Improving the metal fluidity is especially important on
lines that process product at low speeds, i.e., less than about 200
feet/minute. Low-speed processing is common for lines that process
heavy gauge product. Also, some older light-gauge lines still
operate at less than 200 feet/minute.
Extra Smooth Galvanized Sheet
When a very uniform, smooth, matte finish is
required, such as for critical exposed surfaces, both Regular and
Minimum Spangle galvanized sheet can be furnished with an Extra
Smooth finish. The most common finish combination is Minimum
Spangle-Extra Smooth. The "extra smooth" surface is produced by a
separate temper rolling operation after coating. Its
appearance resembles the matte finish of uncoated cold rolled sheet. The use of Extra Smooth Galvanized Sheet is required
when spangle show-through after painting is
unacceptable.
Surface Treatment
U.S. Steel Galvanized Sheet can be specified with five types of
surface treatment:
- Chemical
Treatment
- Oil
- Chemical Treatment
and Oil
- Dry
- Phosphatized
Chemical
Treatment
"Chemical treatment"
consists of the application of a thin, relatively invisible,
corrosion-inhibiting inorganic chemical film on the zinc
surface. This film is applied on the galvanizing line by
dipping into (or spraying on) an aqueous solution of
corrosion-inhibiting chemicals. The chemically treated
surface is much more resistant to "white rust", the corrosion of
zinc that typically occurs when the coils or bundles become wet
through either water intrusion or condensation during storage or
when in transit. White rust, which is simply the white-colored
corrosion products of zinc, is also called "humid-storage
stain".
Chemical treatment does a superior job of:
- Preventing white
rust in coils.
- Maintaining
brightness and delaying the onset of darkening (graying) of sheet
surfaces upon exposure to the atmosphere.
A word of
caution - chemical treatment is not compatible with all
pretreatments used on paint lines to produce prepainted sheet. It
interferes with good adhesion of the paint. In most cases,
galvanized sheet intended for subsequent painting should
not be ordered with chemical treatment.
Oil
Instead of a chemical treatment, galvanized sheet can be
ordered with "oil" to minimize the tendency for humid-storage
stain. A thin coat of rust-preventive oil applied at the mill
prevents white rust in coils and lifts during transit and
short-term high-humidity storage. Oil, unlike chemical
treatment, is not intended to delay darkening of the spangled
surface upon use. It is generally less effective than
chemical treatment as protection against humid-storage
staining.
- Oil is very
effective for preventing roll pickup during rollforming
operations.
- Oil is generally
used instead of a chemical treatment to protect the surface when
the product is intended to be painted. In these applications,
the sheet must be thoroughly cleaned to remove the oil prior to
painting.
Chemical Treatment and Oil
A combination of "chemical treatment and oil" can be specified when
the effectiveness of the chemical treatment is desired for
humid-storage stain resistance and an oil is needed for enhanced
formability. Also, the application of oil over the chemical
treatment provides some enhancement over "chemical treatment only"
to resist humid-storage staining.
Dry
Galvanized sheet is ordered "dry" if neither chemical treatment
nor oil is compatible with the customer's requirements.
Untreated zinc surfaces are very susceptible to humid-storage
stain; moisture intrusion or condensation during shipment or
storage will cause white rust. Galvanized sheet
produced dry must be transported and stored with special
precautions to preserve low-humidity conditions.
Phosphatized
Any galvanized sheet surface finish, such as Regular Spangle or
Minimum Spangle, can be "phosphatized." This product is
specially pretreated at the mill to allow the user to paint in the
as-received condition. The phosphate coating, which provides
enhanced paint adhesion and improved corrosion resistance to the
painted sheet, allows the end user to bypass the treatment step in
his painting operation. The added corrosion resistance is achieved
by an improved protection against undercutting of the paint film
during exposure in the atmosphere.
The phosphate treatment is a relatively
thick, dense, crystalline deposit of hydrated zinc phosphate
compounds on the galvanized surface. After phosphating, the surface
has a dull gray appearance.
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